H4O and other hydrogen-oxygen compounds at giant-planet core pressures

نویسندگان

  • Shuai Zhang
  • Hugh F. Wilson
  • Kevin P. Driver
  • Burkhard Militzer
چکیده

Water and hydrogen at high pressure make up a substantial fraction of the interiors of giant planets. Using ab initio random structure search methods we investigate the ground-state crystal structures of water, hydrogen, and hydrogen-oxygen compounds. We find that, at pressures beyond 14 Mbar, excess hydrogen is incorporated into the ice phase to form a novel structure with H4O stoichiometry. We also predict two new ground state structures, P21/m and I4/mmm, for postC2/m water ice.

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تاریخ انتشار 2012